双磁极式磁粒研磨机理分析及试验研究

目的解决平面磁粒研磨中压力不均匀和需要反复调整研磨间隙的问题,设计双磁极式研磨方法。方法首先对双磁极式研磨方法机理进行分析,并对研磨区域单颗磨粒进行受力分析,寻找影响研磨压力的主要因素;其次利用Ansoft Maxwell软件对两种研磨方法进行磁场仿真,分析两种研磨方法的研磨区域磁场梯度变化,通过面积积分法对比磁感应强度的影响程度;最后设计试验装置,通过试验对理论分析及有限元分析的结果进行验证,对比研磨前后工件表面粗糙度及微观形貌变化。结果双磁极式研磨方法中磨粒的研磨压力完全由磁场力提供,与研磨区域磁感应强度成正比,研磨区域磁感应强度比"铣削式"研磨方法提高约34.56%。两种方法在相同试验条件下对SUS304不锈钢板研磨40 min,双磁极式研磨方法研磨后,工件表面原始纹理基本被去除,表面粗糙度值由原始的0.25μm下降至0.16μm,下降率为36%,比"铣削式"研磨方法提高约80%,粗糙度曲线波动平缓,波峰波谷高度差变化均匀且表面形貌光滑平整。结论双磁极式研磨方法研磨区域磁场梯度变化明显,利于磨粒流动更新,研磨压力相对稳定,表面粗糙度下降率高,研磨后工件表面形貌光整,与"铣削式"研磨方法相比具有较明显的优势。     

Multi-stage intelligent operation optimization for a hydrocracking fractionation system with a multi-fractionator series-parallel structure

A fractionation system is an essential unit in the hydrocracking process. Its optimal operation is challenging because of the complexity in the structure of the distillation tower and composition of the stream. In addition, the series-parallel structure between the distillation towers of different techniques aggravates the coupling and complexity of the hydrocracking fractionation system (HFS). This, in turn, increases the time complexity of the optimization problem. In this paper, a rigorous mechanism model of an actual HFS is first applied to describe the operating conditions of the HFS. Then, an improved state transition algorithm (STA) with a staged evaluation strategy is proposed to solve the above problem. To overcome problems caused by the series-parallel structure of HFS, the model is divided into multiple stages for evaluation by mechanism analysis. Furthermore, several typical convergence estimation criteria are introduced to reduce unnecessary model calculations. To solve time-consuming problems associated with HFS optimization, the adaptive change operator is used to improve the search function of the original algorithm and two performance criteria are presented to reduce the optimization time. The proposed algorithm is successfully applied to the operational parameter optimization problem of HFS with a multi-fractionator series-parallel structure. The experimental results indicated that the staged evaluation strategy improved the fast convergence probability of the HFS mechanism model and reduced unnecessary calculations, whereas the improved algorithm increased accuracy and significantly decreased optimization time.     

离子液体的溶液热力学模型研究进展

离子液体是近年来发展起来的一种绿色介质，在化工反应和分离过程中具有广泛的应用前景。离子液体的溶液热力学性质和相平衡数据是其相关工艺过程设计的基础。本文从如下几个方面综述了离子液体溶液热力学模型的研究进展，即溶液热力学研究方法、溶液热力学模型的构建、离子液体的结构和分子间作用力、离子液体的溶液热力学模型及其在相平衡计算中的应用。重点分析了适用于离子液体溶液热力学性质计算的状态方程模型和过量Gibbs自由能模型或活度系数模型，离子液体的电解质和非电解质溶液模型，以及这些模型对ILs结构、氢键和静电作用的处理方法。分析了这些模型的优缺点，并对今后离子液体的溶液热力学研究提出了建议。     

Classification and identification of gas–liquid dispersion states in a jet bubbling reactor

Three gas–liquid dispersion states including flooding, loading, and complete dispersion are observed sequentially in a jet bubbling reactor with an increase of the liquid jet velocity at the nozzle outlet (u_j). The gas–liquid dispersion states are identified through the slope (k) of the curve of fluctuation distribution index (FI) versus u_j as follows: (a) under the flooding, k = 0; (b) under the loading, k > 0; (c) under the complete dispersion, k < 0. In particular, the u_j at the transition points from flooding to loading and from loading to complete dispersion are referred to flooding jet velocity (u_jf, the transition point between k = 0 and k > 0) and complete dispersion jet velocity (u_jcd, the transition point from k > 0 to k < 0), respectively. The average relative deviations of the u_j at the transition points obtained through the acoustic emission measurement and visual observation are less than 5%.     

Analytical attractive functions and their derivatives in bulk and nanoconfined pores

In this paper, two new analytical attractive (alpha) functions and their derivatives in bulk and nanoconfined pores are developed based on the virial equation of state (EOS) and statistical thermodynamics and are evaluated at different conditions for the first time. A cubic EOS is modified to nanometer scale and applied to predict the thermodynamic and phase properties in bulk and nanoconfined pores coupled with the new analytical alpha functions. The nanoscale-extended EOS coupled with the analytical alpha functions are validated to be accurate by means of the experimental data for the thermodynamic and phase calculations. The alpha functions and dimensionless attractive term A for the O₂, Ar, CO₂, N₂, and C₁-C₁₀ are always positive and monotonically decrease with the temperature increases at T ≤ 2000 K in the bulk phase, whereas the second virial coefficients (B₂) are always negative and increase with the temperature increases. Moreover, the alpha functions, A, and B₂ for all of components remain constant with the decreasing pore radius until r_p = 50 nm, the former two of which decrease while the latter one increases by further reducing the pore radius. It should be noted that the intermolecular attractive force (ie, A) is a function of the pressure, which is gradually increased at P ≤ 10 MPa though drastically increases afterwards. Also, the enhanced confinement effects lead the same-component intermolecular attractive forces to be smaller. The analytical formulations in the SRK type slightly outperform in the gaseous or light component cases, while those in the PR type are better for the heavy component cases in terms of the thermodynamic property calculations, both of which are compatible with the modified EOS and analytical alpha functions.     

Observer‐based fuzzy adaptive quantized control for uncertain nonlinear multiagent systems

This paper focuses on consensus quantized control design problem for uncertain nonlinear multiagent systems with unmeasured states. Every follower can be denoted through a system with unmeasurable states, hysteretic quantized input, and unknown nonlinearities. Fuzzy state observer and Fuzzy logic systems are employed to estimate unmeasured states and approximate unknown nonlinear functions, respectively. The hysteretic quantized input can be split into two bounded nonlinear functions to avoid chattering problem. By combining adaptive backstepping and first‐order filter signals, an observer‐based fuzzy adaptive quantized control scheme is designed for each follower. All signals exist in closed‐loop systems are semiglobally uniformly ultimately bounded, and all followers can accomplish a desired consensus results. Finally, a numerical example is employed to elaborate the effectiveness of proposed control strategy.     

自重湿陷性黄土地基预钻孔浸水处理的可靠度设计方法

为解决传统预浸水法存在的浸水时间长、浸水处理范围难以确定等不足,基于土体中水分运移规律,依据可靠度理论、极限状态设计方法及复合 Poisson 过程原理,提出一种消除黄土湿陷性的处理浸水方法——预钻孔浸水法。给出了利用预钻孔浸水法对自重湿陷性黄土地基进行浸水时,水平向及竖直向浸水影响范围的确定模型;在此基础上结合达西定律给出了浸水孔设计参数如孔深、孔间距及浸水孔个数的确定方法。结合铜川某工程,设计进行了现场预钻孔浸水试验,对该方法的合理性进行了验证,并通过现场钻探、现场勘探、室内湿陷性试验等方法对该方法的处理效果进行了评价。该浸水方法具有浸水时间短、浸水影响范围可根据浸水孔布设进行控制等优点,且浸水处理效果良好,完全符合施工要求。     

Numerical investigation of thermal and electrical management during hydrogen reversible solid-state storage using a novel heat exchanger based on thermoelectric modules

In order to reduce the costs generated by the hydrogen solid storage tank's accessories such as the heat exchanger, this work was carried out. It shows thermal and electrical investigations of transient hydrogen (H₂) solid storage in a tank filled with porous medium (LaNi₅) to activate a potential PEM automotive fuel cell. For this purpose, we use a novel heat exchanger with a heat sink combined with thermoelectric modules (TEMs). We realize a simulation that helps us verify if thermoelectric exchanger will be an alternative to the conventional ones. The main results are that a thermoelectric cooler and heater with 127 couples of semiconductors coupled with 19 fins heat sink could be used during the reversible hydrogen solid storage. Also, results show that we can avoid the water freezing at negative temperatures when using a conventional heat exchanger by using TEM during hydrogen absorption. Finally, during the endothermic desorption of the hydrogen, TEG use can avoid boiling water used in the heating system. Also, the hydrogen tank will be lighter and compact without fins and water tubes.     

基于滚动摩擦作用下玉米颗粒在模拟筒仓卸料中的力链分析（网络首发、推荐阅读）

针对颗粒滚动摩擦作用对筒仓中玉米颗粒的力链空间分布进行研究，通过EDEM离散元软件建立筒仓模型与仿真玉米颗粒模型进行卸粮仿真模拟，并与筒仓卸料实验作流态对比，验证模型与仿真结果的准确性。通过对模拟仓进行切片观察和数据处理，对比分析了不同摩擦情况下力链的细观参数随时间演化规律。模拟结果表明：颗粒间摩擦系数越大，卸粮完成的最终时间越长；颗粒间滚动摩擦系数越小，颗粒由整体流转变为管状流的时间越早。对于有漏斗的筒仓来说，减小颗粒间摩擦会改变整体流和管状流之间的极限，从而增加产生管状流的面积。标准滚动摩擦系数下玉米颗粒在卸料过程中会出现起拱-塌陷效应；减小滚动摩擦，玉米颗粒卸料较稳定，未出现起拱的应力突增、以及拱塌陷的应力衰减；增大颗粒间滚动摩擦不但会增加拱效应，且出现成拱高度距离漏斗口更高。     

Estimates for the local permeability of the Cobourg limestone

Argillaceous limestone formations are being proposed as sites suitable for constructing a deep geologic repository for storing low-to intermediate-level nuclear waste in southern Ontario, Canada. The Cobourg limestone is characterized by a visual appearance of heterogeneity resulting from light gray calcite nodular regions interspersed with dark gray calcite-dolomite-quartz partings containing a clay component. This paper presents the results of experiments conducted to determine the permeability of both the light gray and the dark gray species of the Cobourg limestone. The permeabilities were successfully estimated from both steady state and hydraulic pulse tests conducted using specially designed miniature water entry ports, which were epoxied to the surface of the rock sample containing cavities drilled into the rock species of interest. The results show that the dark gray species of the Cobourg limestone has a permeability that is roughly one order of magnitude greater than the light gray calcite species.